# Two Types Of Diffraction

Fraunhofer's diffraction:- This type of diffraction takes place at a narrow slit when parallel rays of light (or plane wavefront) are incident on it. Clearly both the source and the screen should be at infinite distance from the narrow slit. To obtain Fraunhofer's diffraction in the laboratory, we use a conversing lens. The bending of light the diffraction effect depends upon the size of the obstacle. Diffraction effects are large if the edges of the obstacle are sharp and aperture is comparable in size of the wavelength of light of the order of 10 ¯7 m. Diffraction of light is of two types: Fresnel Diffraction; Fraunhofer diffraction.

Examples and Application of diffraction in real life: 1. CD reflecting rainbow colours 2. Sun appears red during sunset 4. From the shadow of an object 5. Bending of light at the corners of the door 1. X-ray diffraction 3. To separate white light.

Take a look at the diagram below:

- When X-rays interact with a single particle, it scatters the incident beam uniformly in
**all**directions. - When X-rays interact with a solid material the scattered beams can add together in a few directions and reinforce each other to yield diffraction. The regularity of the material is responsible for the diffraction of the beams.

You have likely seen diffraction before. For example if you look at a CD when exposed to white light you can see it diffracted into varies wavelengths of color. The pits (or grooves) in the CD are the regularity of the material that causes the diffraction.

Google images: outreach.atnf.csiro.au

Diffraction can occur when any electromagnetic radiation interacts with a periodic structure. The repeat distance of the periodic structure must be about the same wavelength of the radiation. For example, light can be diffracted by a grating having scribed lines arranged on the order of the wavelength of light.

Exercise (PageIndex{1})

So if all electromagnetic radiation can diffract, why are X-rays used in crystallography?

## X-ray Diffraction and Bragg’s Law

X-rays have wavelengths on the order of a few angstroms (1 Angstrom = 0.1 nm). This is the typical inter-atomic distance in crystalline solids, making X-rays the correct order of magnitude for diffraction of atoms of crystalline materials.

### How are Diffractions Patterns Made?

When X-rays are scattered from a crystalline solid they can constructively interfere, producing a diffracted beam. **What does this mean?**

#### Constructive vs. Destructive Interference

Interference occurs among the waves scattered by the atoms when crystalline solids are exposed to X-rays. There are two types of interference depending on how the waves overlap one another.

Constructive interference occurs when the waves are moving in phase with each other. Destructive interference occurs when the waves are out of phase.

This constructive interference results in diffraction patterns.

### Bragg's Law and Diffraction

The relationship describing the angle at which a beam of X-rays of a particular wavelength diffracts from a crystalline surface was discovered by Sir William H. Bragg and Sir W. Lawrence Bragg and is known as Bragg’s Law

[mathrm{2dsin θ= nλ}]

λ = wavelength of the x-ray

## List Two Types Of Diffraction

θ = scattering angle

n = integer representing the order of the diffraction peak.

d = inter-plane distance of (i.e atoms, ions, molecules)

Click on the following image below to get to an Applet where you can explore this relationship of Bragg’s Law

www.eserc.stonybrook.edu/ProjectJava/Bragg/

__Guide to how to use Applet:__ There are 2 rays incident on two atomic layers of a crystal (d). At the beginning the scattered rays are in phase and interfering constructively. Bragg’s Law is satisfied and diffraction is occurring. If you click on the details button you can see the detector, which measures how well the phases of the two rays match. When the meter is green it indicates that Bragg’s law is satisfied. You can change three variables (d, λ, and θ) to see how they effect the diffraction.

Exercise (PageIndex{2}): Unit Cell Size from Diffraction Data

The diffraction pattern of copper metal was measured with X-ray radiation of wavelength of 1.315Å. The first order Bragg diffraction peak was found at an angle 2theta of 50.5 degrees. Calculate the spacing between the diffracting planes in the copper metal.

### Learning Objectives

By the end of this section, you will be able to:

- Discuss the pattern obtained from diffraction grating.
- Explain diffraction grating effects.

Figure 1. The colors reflected by this compact disc vary with angle and are not caused by pigments. Colors such as these are direct evidence of the wave character of light. (credit: Infopro, Wikimedia Commons)

An interesting thing happens if you pass light through a large number of evenly spaced parallel slits, called a *diffraction grating*. An interference pattern is created that is very similar to the one formed by a double slit (see Figure 2). A diffraction grating can be manufactured by scratching glass with a sharp tool in a number of precisely positioned parallel lines, with the untouched regions acting like slits. These can be photographically mass produced rather cheaply. Diffraction gratings work both for transmission of light, as in Figure 2, and for reflection of light, as on butterfly wings and the Australian opal in Figure 3 or the CD in Figure 1. In addition to their use as novelty items, diffraction gratings are commonly used for spectroscopic dispersion and analysis of light. What makes them particularly useful is the fact that they form a sharper pattern than double slits do. That is, their bright regions are narrower and brighter, while their dark regions are darker. Figure 4 shows idealized graphs demonstrating the sharper pattern. Natural diffraction gratings occur in the feathers of certain birds. Tiny, finger-like structures in regular patterns act as reflection gratings, producing constructive interference that gives the feathers colors not solely due to their pigmentation. This is called iridescence.

Figure 1. A diffraction grating is a large number of evenly spaced parallel slits. (a) Light passing through is diffracted in a pattern similar to a double slit, with bright regions at various angles. (b) The pattern obtained for white light incident on a grating. The central maximum is white, and the higher-order maxima disperse white light into a rainbow of colors.

Figure 2. (a) This Australian opal and (b) the butterfly wings have rows of reflectors that act like reflection gratings, reflecting different colors at different angles. (credits: (a) Opals-On-Black.com, via Flickr (b) whologwhy, Flickr)

Figure 4. Idealized graphs of the intensity of light passing through a double slit (a) and a diffraction grating (b) for monochromatic light. Maxima can be produced at the same angles, but those for the diffraction grating are narrower and hence sharper. The maxima become narrower and the regions between darker as the number of slits is increased.

The analysis of a diffraction grating is very similar to that for a double slit (see Figure 5). As we know from our discussion of double slits in Young’s Double Slit Experiment, light is diffracted by each slit and spreads out after passing through. Rays traveling in the same direction (at an angle *θ* relative to the incident direction) are shown in Figure 5. Each of these rays travels a different distance to a common point on a screen far away. The rays start in phase, and they can be in or out of phase when they reach a screen, depending on the difference in the path lengths traveled.

As seen in Figure 5, each ray travels a distance *d* sin *θ* different from that of its neighbor, where *d* is the distance between slits. If this distance equals an integral number of wavelengths, the rays all arrive in phase, and constructive interference (a maximum) is obtained. Thus, the condition necessary to obtain *constructive interference for a diffraction grating* is *d* sin *θ = mλ, *for *m* = 0, 1, −1, 2, −2, . . . (constructive) where *d* is the distance between slits in the grating, *λ* is the wavelength of light, and *m* is the order of the maximum. Note that this is exactly the same equation as for double slits separated by *d*. However, the slits are usually closer in diffraction gratings than in double slits, producing fewer maxima at larger angles.

In Figure 5, we see a diffraction grating showing light rays from each slit traveling in the same direction. Each ray travels a different distance to reach a common point on a screen (not shown). Each ray travels a distance *d* sin *θ* different from that of its neighbor.

Where are diffraction gratings used? Diffraction gratings are key components of monochromators used, for example, in optical imaging of particular wavelengths from biological or medical samples. A diffraction grating can be chosen to specifically analyze a wavelength emitted by molecules in diseased cells in a biopsy sample or to help excite strategic molecules in the sample with a selected frequency of light. Another vital use is in optical fiber technologies where fibers are designed to provide optimum performance at specific wavelengths. A range of diffraction gratings are available for selecting specific wavelengths for such use.

### Take-Home Experiment: Rainbows on a CD

The spacing *d* of the grooves in a CD or DVD can be well determined by using a laser and the equation *d* sin *θ = mλ, *for*m* = 0, 1, −1, 2, −2, . . . . However, we can still make a good estimate of this spacing by using white light and the rainbow of colors that comes from the interference. Reflect sunlight from a CD onto a wall and use your best judgment of the location of a strongly diffracted color to find the separation *d*.

### Example 1. Calculating Typical Diffraction Grating Effects

Diffraction gratings with 10,000 lines per centimeter are readily available. Suppose you have one, and you send a beam of white light through it to a screen 2.00 m away.

- Find the angles for the first-order diffraction of the shortest and longest wavelengths of visible light (380 and 760 nm).
- What is the distance between the ends of the rainbow of visible light produced on the screen for first-order interference? (See Figure 6.)

Figure 6. The diffraction grating considered in this example produces a rainbow of colors on a screen a distance from the grating. The distances along the screen are measured perpendicular to the x-direction. In other words, the rainbow pattern extends out of the page.

#### Strategy

## What Is An Example Of Diffraction

The angles can be found using the equation *d* sin *θ = mλ (*for*m* = 0, 1, −1, 2, −2, . . . ) once a value for the slit spacing *d* has been determined. Since there are 10,000 lines per centimeter, each line is separated by 1/10,000 of a centimeter. Once the angles are found, the distances along the screen can be found using simple trigonometry.

#### Solution for Part 1

The distance between slits is [latex]d=frac{1text{ cm}}{10,000}=1.00times10^{-4}text{ cm}[/latex] or 1.00 × 10^{−6} m. Let us call the two angles *θ*_{V} for violet (380 nm) and *θ*_{R} for red (760 nm). Solving the equation *d* sin θ_{V}* = mλ* for sin θ_{V}, [latex]sintheta_{text{V}}=frac{mlambda_{text{V}}}{d}[/latex], where *m *= 1 for first order and *λ*_{V} = 380 nm = 3.80 × 10^{−7} m. Substituting these values gives

[latex]displaystylesintheta_{text{V}}=frac{3.80times10^{-7}text{ m}}{1.00times10^{-6}text{ m}}=0.380[/latex]

Thus the angle *θ*_{V} is *θ*_{V} = sin^{−1} 0.380 = 22.33º.

Similarly,

[latex]displaystylesintheta_{text{R}}=frac{7.60times10^{-7}text{ m}}{1.00times10^{-6}text{ m}}[/latex]

## What Are The Two Types Of Diffraction

Thus the angle *θ*_{R} is *θ*_{R} = sin^{−1} 0.760 = 49.46º.

Notice that in both equations, we reported the results of these intermediate calculations to four significant figures to use with the calculation in Part 2.

#### Solution for Part 2

The distances on the screen are labeled *y*_{V} and *y*_{R} in Figure 6. Noting that [latex]tantheta=frac{y}{x}[/latex], we can solve for *y*_{V} and *y*_{R}. That is, *y*_{V} = *x *tan *θ*_{V} = (2.00 m)(tan 22.33º) = 0.815 m and *y*_{R} = *x *tan *θ*_{R} = (2.00 m)(tan 49.46º) = 2.338 m.

The distance between them is therefore *y*_{R} − *y*_{V} = 1.52 m.

#### Discussion

The large distance between the red and violet ends of the rainbow produced from the white light indicates the potential this diffraction grating has as a spectroscopic tool. The more it can spread out the wavelengths (greater dispersion), the more detail can be seen in a spectrum. This depends on the quality of the diffraction grating—it must be very precisely made in addition to having closely spaced lines.

## Section Summary

A diffraction grating is a large collection of evenly spaced parallel slits that produces an interference pattern similar to but sharper than that of a double slit.

There is constructive interference for a diffraction grating when d sin *θ *= *mλ* (for *m* = 0 , 1, –1, 2, –2, …), where *d* is the distance between slits in the grating, *λ* is the wavelength of light, and* m *is the order of the maximum.

### Conceptual Questions

- What is the advantage of a diffraction grating over a double slit in dispersing light into a spectrum?
- What are the advantages of a diffraction grating over a prism in dispersing light for spectral analysis?
- Can the lines in a diffraction grating be too close together to be useful as a spectroscopic tool for visible light? If so, what type of EM radiation would the grating be suitable for? Explain.
- If a beam of white light passes through a diffraction grating with vertical lines, the light is dispersed into rainbow colors on the right and left. If a glass prism disperses white light to the right into a rainbow, how does the sequence of colors compare with that produced on the right by a diffraction grating?
- Suppose pure-wavelength light falls on a diffraction grating. What happens to the interference pattern if the same light falls on a grating that has more lines per centimeter? What happens to the interference pattern if a longer-wavelength light falls on the same grating? Explain how these two effects are consistent in terms of the relationship of wavelength to the distance between slits.
- Suppose a feather appears green but has no green pigment. Explain in terms of diffraction.
- It is possible that there is no minimum in the interference pattern of a single slit. Explain why. Is the same true of double slits and diffraction gratings?

### Problems & Exercises

- A diffraction grating has 2000 lines per centimeter. At what angle will the first-order maximum be for 520-nm-wavelength green light?
- Find the angle for the third-order maximum for 580-nm-wavelength yellow light falling on a diffraction grating having 1500 lines per centimeter.
- How many lines per centimeter are there on a diffraction grating that gives a first-order maximum for 470-nm blue light at an angle of 25.0º?
- What is the distance between lines on a diffraction grating that produces a second-order maximum for 760-nm red light at an angle of 60.0º?
- Calculate the wavelength of light that has its second-order maximum at 45.0º when falling on a diffraction grating that has 5000 lines per centimeter.
- An electric current through hydrogen gas produces several distinct wavelengths of visible light. What are the wavelengths of the hydrogen spectrum, if they form first-order maxima at angles of 24.2º, 25.7º, 29.1º, and 41.0º when projected on a diffraction grating having 10,000 lines per centimeter?
- (a) What do the four angles in the above problem become if a 5000-line-per-centimeter diffraction grating is used? (b) Using this grating, what would the angles be for the second-order maxima? (c) Discuss the relationship between integral reductions in lines per centimeter and the new angles of various order maxima.
- What is the maximum number of lines per centimeter a diffraction grating can have and produce a complete first-order spectrum for visible light?
- The yellow light from a sodium vapor lamp seems to be of pure wavelength, but it produces two first-order maxima at 36.093º and 36.129º when projected on a 10,000 line per centimeter diffraction grating. What are the two wavelengths to an accuracy of 0.1 nm?
- What is the spacing between structures in a feather that acts as a reflection grating, given that they produce a first-order maximum for 525-nm light at a 30.0º angle?
- Structures on a bird feather act like a reflection grating having 8000 lines per centimeter. What is the angle of the first-order maximum for 600-nm light?
- An opal such as that shown in Figure 2 acts like a reflection grating with rows separated by about 8 μm. If the opal is illuminated normally, (a) at what angle will red light be seen and (b) at what angle will blue light be seen?
- At what angle does a diffraction grating produces a second-order maximum for light having a first-order maximum at 20.0º?
- Show that a diffraction grating cannot produce a second-order maximum for a given wavelength of light unless the first-order maximum is at an angle less than 30.0º.
- If a diffraction grating produces a first-order maximum for the shortest wavelength of visible light at 30.0º, at what angle will the first-order maximum be for the longest wavelength of visible light?
- (a) Find the maximum number of lines per centimeter a diffraction grating can have and produce a maximum for the smallest wavelength of visible light. (b) Would such a grating be useful for ultraviolet spectra? (c) For infrared spectra?
- (a) Show that a 30,000-line-per-centimeter grating will not produce a maximum for visible light. (b) What is the longest wavelength for which it does produce a first-order maximum? (c) What is the greatest number of lines per centimeter a diffraction grating can have and produce a complete second-order spectrum for visible light?
- A He–Ne laser beam is reflected from the surface of a CD onto a wall. The brightest spot is the reflected beam at an angle equal to the angle of incidence. However, fringes are also observed. If the wall is 1.50 m from the CD, and the first fringe is 0.600 m from the central maximum, what is the spacing of grooves on the CD?
- The analysis shown in the figure below also applies to diffraction gratings with lines separated by a distance
*d*. What is the distance between fringes produced by a diffraction grating having 125 lines per centimeter for 600-nm light, if the screen is 1.50 m away?Figure 6. The distance between adjacent fringes is [latex]Delta y=frac{xlambda}{d}[/latex], assuming the slit separation d is large compared with λ.

**Unreasonable Results.**Red light of wavelength of 700 nm falls on a double slit separated by 400 nm. (a) At what angle is the first-order maximum in the diffraction pattern? (b) What is unreasonable about this result? (c) Which assumptions are unreasonable or inconsistent?**Unreasonable Results.**(a) What visible wavelength has its fourth-order maximum at an angle of 25.0º when projected on a 25,000-line-per-centimeter diffraction grating? (b) What is unreasonable about this result? (c) Which assumptions are unreasonable or inconsistent?**Construct Your Own Problem.**Consider a spectrometer based on a diffraction grating. Construct a problem in which you calculate the distance between two wavelengths of electromagnetic radiation in your spectrometer. Among the things to be considered are the wavelengths you wish to be able to distinguish, the number of lines per meter on the diffraction grating, and the distance from the grating to the screen or detector. Discuss the practicality of the device in terms of being able to discern between wavelengths of interest.

## Glossary

**constructive interference for a diffraction grating:** occurs when the condition *d* sin *θ* = *mλ* (form = 0,1,–1,2,–2, . . .) is satisfied, where d is the distance between slits in the grating, λ is the wavelength of light, and m is the order of the maximum

## Distinguish Between Two Types Of Diffraction Of Light

**diffraction grating:** a large number of evenly spaced parallel slits

### Selected Solution to Problems & Exercises

1. 5.97º

3. 8.99 × 10^{3}

5. 707 nm

7. (a) 11.8º,12.5º,14.1º,19.2º; (b) 24.2º,25.7º,29.1º,41.0º; (c) Decreasing the number of lines per centimeter by a factor of *x* means that the angle for the *x*-order maximum is the same as the original angle for the first-order maximum.

9. 589.1 nm and 589.6 nm

11. 28.7º

13. 43.2º

15. 90.0º

17. (a) The longest wavelength is 333.3 nm, which is not visible; (b) 333 nm (UV); (c) 6.58 × 10^{3} cm

19. 1.13 × 10^{−2} m

## Grating Diffraction

21. (a) 42.3 nm; (b) Not a visible wavelength. The number of slits in this diffraction grating is too large. Etching in integrated circuits can be done to a resolution of 50 nm, so slit separations of 400 nm are at the limit of what we can do today. This line spacing is too small to produce diffraction of light.